A lithium-ion battery fire is almost impossible to put out. We look at why that is, how fire services are handling it and what can be done to minimise risks.
As more electric cars take to roads, attention is turning to their safety, in particular fire safety.
No matter that petrol and diesel cars can catch fire and many of them do, an electric vehicle fire commands a lot more attention for a few reasons:
- The technology is new.
- EV fires are complex and often heralded by a highly toxic vapour cloud accompanied by a hissing noise and highly directional jets, followed, possibly, by an explosion.
- They can occur spontaneously.
- Putting out an EV fire is virtually impossible. You think it’s out and then it erupts again hours, days or even weeks later.
All this considered, it’s no wonder people are becoming concerned about electric car fires, not least those who have to put them out.
Experts are divided on how best to tackle an EV fire but, generally, immense quantities of water to cool the battery pack (although this won’t prevent fire erupting again), a fire blanket to suppress the flames and breathing equipment for the fire fighters to protect them from the toxic vapour cloud is the standard approach. Either that or simply let the blaze burn itself out. Attempting to suffocate the fire with inert gases is ineffective because, being a chemical blaze, it does not require oxygen. Meanwhile, the surrounding area must be checked for discarded battery cells that could have been propelled from the battery pack by an explosion and might spontaneously ignite later. Following containment, the burnt-out EV must be removed and deposited in a compound away from buildings and other vehicles. More radical steps include immersing the car in water, although not seawater because chlorine gas can be released.
It all sounds quite alarming and a good reason not to buy an electric car, but Paul Christensen, professor of pure and applied electrochemistry at Newcastle University and senior advisor to the UK’s National Fire Chiefs Council (NFCC), is keen to quell fears about EV fire safety, especially given the benefits the technology offers.
“As someone who assisted Nissan during the creation of its battery plant, I would, if I could afford one, have a Nissan Leaf tomorrow,” he says. “We don’t need to be worried about the small incidence of fires involving electric vehicles but we do need to be aware. A lithium ion battery stores a huge amount of energy in a very small space. Since 2008, the adoption of such batteries has outstripped our appreciation of their risks. We’re running to catch up but we will do.”
As part of his campaign to improve EV fire risk awareness among first responders, Christensen has, so far, presented to 30 of the UK’s 50 fire services, as well as to fire services in Australia, Europe and New Zealand. He begins each talk by describing the structure of a lithium ion battery cell. A sliver of aluminium, called the cathode, is coated with a mixed-metal oxide ink. It’s partnered by a slice of copper coated with graphite called the anode. In between them is a fragile, perforated plastic separator soaked in an organic solvent that contains a small quantity of additives whose identity is, troublingly, known only to the cell manufacturer. Depending on whether the battery is being charged or discharged, the lithium ions move either from, or to, the cathode and anode.
Then the professor gives his audience of firefighters their first shock. Full, a cell contains 4.2V of charge, but even when empty, it still holds 2.5V. A Nissan Leaf has from around 192 cells in 24 modules and a Tesla Model S over 7000 in 16 modules. That’s a lot of energy when the car’s power indicator says it has none. Full or ‘empty’, the risk of this energy escaping in an uncontrolled fashion is what some scientists believe leads to ‘thermal runaway’, when heat and gases fuel even higher temperatures and still more gases, including hydrogen and oxygen, in a self-fulfilling loop until the cells begin to burn and burst. A toxic vapour cloud develops, bringing with it the risk of deflagration. Once thermal runaway has started, no battery management system or circuit breaker can stop it. “A battery fire can be controlled but it cannot be extinguished,” says Christensen.
He has demonstrated in tests how perforating or otherwise damaging a battery pack, as in a crash, can cause it to catch fire. “If an EV’s battery case is dented, you have to assume it’s dangerous,” he says. Battery packs have been known to catch fire through overheating and while being charged. More worrying, a battery fire can erupt spontaneously, contamination of even just a single cell during its manufacture being one possible explanation. “Even the most experienced and careful manufacturers have defective electric cells passing through their very careful quality control systems,” says Christensen.
A battery flame is like a blowtorch that will quickly ignite anything in its path, which is why Christensen wants councils and other organisations to consider EV safety risks in underground car parks, as well as bus depots where vehicles are parked side by side. “In Germany, three bus depots have gone up in flames in the past six or so months,” he says. “Tunnels, ferries, car parks, cargo ships transporting EVs – all the places you find electric vehicles should be considered a safety risk and the appropriate steps taken.”
He’s worried about classic cars being converted to run on used lithium ion batteries, too. “Nobody really knows how safe used lithium ion batteries are and no standard test has yet been devised to tell us,” he says. “Some batteries re-enter the market having been removed in illegal chop shops. How safe are they? There’s a lot of research into lithium ion battery safety but everyone needs to link up because, right now, we’re at the bottom of a very steep learning curve.”
When all else fails…
For electric cars that are on fire or at risk of being so, the fire service in Copenhagen, Denmark, has developed a truck-mounted vehicle containment solution. The smouldering EV is lowered into the container, which, like a skip, is then hoisted onto a flatbed truck. Nozzles in the floor and sides of the container allow water to be pumped into it. Once full, container and car are taken to a safe storage area and left, possibly for weeks, until the vehicle is no longer a hazard. All being well, the water is then filtered and treated for its safe disposal.
John Evans